To answer your original question, I would definitely go with just doing them on observed heats but get some patches to help you out. With observed heats you get to ease into putting into practice what you learnt. If you synchronise them you will have a group to do all at once, if things don't go as you planned you may get into a panic and not be able to do any.
Most importantly get organised, set things out on a table and rehearse the preparation before hand. It is important that you have the thawing and loading under control so that you don't get flustered and can relax and take your time to do the actual insemination. This is why I recommend the doing them as you observe heats rather than synchronise several together.
Remember it takes a lot of practice and each one is different, take your time and work through it.
Ken