If you're worried, you could buy a bloat block and keep it in the pasture with the calf. BUT, the animal has to be on the bloat block for 2 days BEFORE it is given free choice on a new kind of feed. And, the animal has to have access to that bloat block every day so it gets a daily dose of the medication contained in the bloat block. After the animal's system adjusts to the new food, the bloat block isn't necessary. We usually use bloat blocks when we first turn our cows out, but after a couple of weeks we pull the blocks and put the remains away for the next season. We don't have year 'round pasture, so we are a little more careful than most. Maybe too careful, but we've never lost a cow to bloat yet.
The diarrhea you are seeing is most likely just the usual loose, liquid runny, green stuff most every cow gets when on spring grass, or when newly turned out on grass.
A second idea is to just turn your calf out on grass for a couple of hours each day for a week or two, feeding its regular food for the other 22 hours a day. That would give its body a chance to adjust gradually. Just increase the time out on pasture as the couple of weeks goes by, until it has free choice to the pasture.
New spring grass doesn't have the nutrition that a little more mature grass has, so your calf may still need some supplementation for a little while.
It's just that a ruminant animal must adjust to new feed gradually or it runs the risk of bloating.