I did about 40 of them like that last year Arnold. It worked in a large % of the trees, but not in all. Some stumps sprouted a dozen suckers up from the cut stump and those are more difficult to treat than anything else.
The big ones I have left are all on either fencelines or next to waterways, which means losing the fences temporarily. I prefer those just die naturally in place. Last fall, I hacked and squirted a lot of them. Leaves turned black the next day. Bark cracked and fell off within a week and all the leaves were gone and I had no shoots coming up that following spring. For reasons I don't understand, fall frill or cut and squirt results in the herbicide going straight to the root system. Maybe the vascular system only works in one direction in the fall--downward. Foliar application in fall tho, is useless for the most part if the leaves have already began to change color. According to what I've read, in mid to late fall, clorophyll production stops and the tree creates a little sappy "plug" at each leaf stem, preventing moisture, starches, and nutrients from entering the leaves--and preventing anything in the leaves from going back into the twigs, limbs and trunks.
To me, autumn seems to be a better time to get a good kill of the root system using cut and spray or injection as long as it isn't too late. If ya wait to late, It might kill that trunk, but a dozen new ones will sprout up from the roots of the same tree.