If you are not familiar with 2,4,D, you should google dicots and google monocots. 2,4,D will kill any dicot. That includes pecan, fruit trees, practically all hardwoods, and most desireable vegtation that is a dicot variety. It will not harm monocots.
When spraying pastures, I found it best to mix to the maximum strength on the label. For my concentration this year, it was 4 pints to 60 gallons of water. It had positive results.
Chemicals can be obtained in a variety of concentrations dependant upon the vendor who furnished it. READ LABELS I once ran out of a pesticide and went and bought more from a different store (that was open). The mixing ratio was much different. I almost made a serious mistake assuming it was the same.