Important Characteristics of 2,4-D
Volatility - volatility refers to the tendency of a chemical to vaporize. Vapor drift is the movement of herbicide vapor off-target. The level of volatility of a chemical is related to the compounds vapor pressure. The amine and sodium salts of 2,4-D are generally considered to be of minimal volatility hazard. Ester formulations, however, are volatile compounds. Most current, commercial 2,4-D ester formulations are termed "low-volatile", but keep in mind that they remain potentially volatile compounds. Under hot and humid conditions the volatility hazard increases. Consequently, extreme care should be taken when applying 2,4-D and other hormone-type herbicides.
Salt Formulations - amine salts are the most commonly used form. The amine salts of 2,4-D are not considered volatile; however, windy conditions can cause physical drift of the herbicide onto susceptible plants. Most amine salts readily dissolve in water to form clear solutions.
Ester Formulations - esters are essentially insoluble in water. The ester is diluted in oil with an emulsifying agent added. When mixed with water, the emulsifier keeps the tiny oil-like droplets suspended, much the way butterfat is suspended in milk. When mixed with water, the 2,4-D emulsion appears milky colored. Ester formulations are generally considered to be slightly more active than the salt formulations and are more susceptible to volatility.