:welcome: from New York
First thing is to find an AI tech in your area. I would have to "assume" you do not have your own nitrogen tank. So, if not, you have to have someone hold the semen for you in their tank. Maybe you have neighbors that have one.
"Most" companies will only sell 5 units at a time - but there are some that will sell singles. Shipping will cost you more than the semen in a lot of cases when only buying very small amounts. Check out ABS and Genex. They deliver free. Plan ahead - may take a month or two to get your semen delivered.
Standing heat means that the one in heat will STAND when another cow mounts her (like a bull). The one on the bottom, standing, is the one in heat. If the one on the bottom jumps/runs away, it is probably the one doing the jumping that is actually in heat. You have to spend time in the morning & evening watching them. They will get very "perky" when they are in heat and they usually will have a clear discharge from their vulva, and the vulva will usually swell & look a little shiny.
You can give shots to both to make them come in at the same time or just observe them & write down when you see them in heat. You can expect them to cycle again 17-19 days later (cows normal time is 21 days but heifers usually have a short heat cycle). So mark it on your calandar & watch to breed.
There are patches (K-Mar) and other scratch off patches that are a great AID. You still need to SEE observed heats. When you see one standing, she should be bred about 12 hours later. Rule of thumb. If standing in the morning - breed in the evening. When standing in the evening - breed in the morning.