Yep. With that many of varied ages all dead BAM! at one time... it's almost got to be a toxin - and most likely high nitrates or cyanide. He needed to have had a veterinarian out ASAP, or gotten some of those deads to the veterinary diagnostic lab pronto.
The Japanese yew deal is very common - often neighbors(or sometimes the owner themselves) think they're giving the cows a 'treat' by throwing clippings over the fence to them. Disaster is in the offing... And... old, dead, brown yew shrubs or clippings will kill them just like a fresh green one... and don't think the darned cows won't eat 'em!
Saw one case where a farmer asked his wife to go put out a bag of salt for the cows, and she unknowingly filled the feeder with ammonium nitrate fertilizer... soon had dead cows piled up all around the mineral feeder.
Botulism... a possibility, but usually losses are spread out and animals don't just drop over dead with no sign of abnormality; usually takes 'em several days to die.
While we're throwing out possibilities...
Any chance of lightning strike, downed powerline, or electrical wire to outbuilding shorting out on metal siding and electrifying the ground, etc., causing electrocution? Have seen all three of those scenarios on more than one occasion, and if it's a live-wire deal, people in the area are at risk!
And... since the most common things happen most often... gotta consider this option... you/he say they were 'healthy on the outside'... but by any chance are they are really a starvation case? Down here, the old saw is, "February breaks 'em, March takes 'em"... if they've toughed the winter through on nothing but low quality hay, sometimes they just 'run out of gas' with green grass just around the corner. Seen it happen way too many times over the past 35 years... and folks want to claim that there's some pathogen or toxin in the hay, when it's just... not enough energy or protein to support life. Again, it would be unusual to have 5 go down and die overnight from starvation... but it could happen.
And... I've seen animals dead for several days that the less-than-observant owner didn't notice... and all of a sudden, "OMG these all died last night!" If you're not actually LOOKING at your cows every day, it can happen - I know... I've been that guy.